The first lead measurements from the Amundsen Sea

Efforts to reduce industrial emissions of lead have been ongoing for several decades. The near-global phase-out of leaded automobile gasoline has showed decreases in environmental lead contamination. A reasonable expectation is that industrial lead concentrations have also measurably decreased in the Southern Ocean. Since lead also has natural sources, a group of scientists decided to examine the relative importance of anthropogenic lead in the Amundsen Sea, a shelf region of West Antarctica, in the first measurements of this sort.

The global scale of lead (Pb) contamination from industrial sources has been well documented; anthropogenic lead, mainly from combustion of leaded gasoline, has been detected in remote sites including samples of Arctic and Antarctic surface ice and ocean deep waters. However, decreases in environmental Pb-contamination following the near-global phase-out of leaded automobile gasoline, beginning in the 1970s, have since been observed.

- Consequently, a reasonable expectation is that industrial Pb-concentrations have also measurably decreased in the Southern Ocean following the virtual elimination of leaded gasoline in the Southern Hemisphere, Kuria Ndungu, a Research Scientist at The Norwegian Institute for Water Research, says.

In a recent study, published as the cover article in the current issue of Environmental Science & Technologyjournal, Ndungu and American colleagues tested this hypothesis in the Amundsen Sea, a shelf region of West Antarctica in the Southern Ocean.

 

AmundsenSea
The Amundsen Sea continental shelf spans about 315000 km2 and extends approximately 300 km in an east−west direction. (Map: Wikimedia Commons)

- We chose this region because the effects of global climate change in West Antarctica are especially pronounced: Glaciers that drain into the Amundsen Sea Embayment are among the world’s fastest dischargers of ice into the ocean, Ndungu says.

The scientists measured both Pb concentrations and Pb isotope compositions of seawater and sediments.

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A sampling rosette with 12 bottles being lowered into the sea to sample water. (Photo: Robert Sherrell, Rutgers University)

- The results of our study show that most (∼60− 95%) of the lead at our sites, at the time of sampling, is natural in source: that is, derived from the weathering of Antarctic continental rocks, says Ndungu.

- As climate change continues to drive ocean circulation changes, we hypothesize that the overall flux of lead in the Amundsen Sea will decrease, as industrial atmospheric lead emissions continue to decline.

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Ndungu taking a break from sampling during on a nice Antarctica summer day. (Photo: Robert Sherrell, Rutgers University).

The scientists conclude that lead budgets for this region are projected to change over the next few decades.

- We also hypothesize that a greater proportion of that Pb flux will be natural Pb from sedimentary sources and basal meltwater, which is thousands of years old, due to changes in ocean circulation. As a result, Pb budgets for this region, and for the greater Southern Ocean, are projected to change over the next few decades as a result of both reductions in atmospheric emissions of industrial lead and increases in atmospheric emissions of industrial CO2, Kuria Ndungu concludes.

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Seawater and sediment samples were collected during the NBP 10−05 ASPIRE cruise (13 Dec 2010−12 Jan 2011) aboard the icebreaker Nathaniel B. Palmer. Pictured here is Swedish ice breaker Oden paving the way for Nathaniel B. Palmer to enter McMurdo Research Station in Antarctica at the end of the two month research cruise. (Photo: Kuria Ndungu, NIVA)

Reference:

Ndungu et al (2016): “Lead Sources to the Amundsen Sea, West Antarctica” in Environ. Sci. Technol., 2016, 50 (12), pp 6233–6239 DOI: 10.1021/acs.est.5b05151

Last updated 01.07.2016